Citation: MA Zhi-Feng, ZHANG Ying-Hui, HU Tong-Liang*, BU Xian-He. Three Cobalt(Ⅱ) Complexes Based on Isomeric Carboxylate-Based Flexible Ligands:Syntheses, Structures and Magnetism[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 204-212. doi: 10.11862/CJIC.2014.078
-
Three Co(Ⅱ) complexes based on E-3-[3-(carboxymethoxy)-phenyl]acrylic acid (H2L1) or E-3-[3-(carboxymethoxy)-phenyl]acrylic acid (H2L2), namely [Co(L1)(bpp)]n(1), {[Co(μ3-OH)2(L2)4(bpy)2(H2O)4]·12H2O}n (2), and [Co(L2)(bpy)]n(3) (bpp: 1,3-bi(pyridin-4-yl)propane, bpy: 4,4-bipyridine), were synthesized and characterized by elemental analysis, IR, XRPD and X-ray single-crystal structure analysis. Different coordination environment for Co(Ⅱ) ions and thereby different crystal structures and magnetism were observed for these three complexes. The magnetic properties of complexes 1 and 2 were discussed in detail.
-
-
[1]
[1] Karmakar T K, Ghosh B K, Usman A, et al. Inorg. Chem., 2005, 44:2391-2393
-
[2]
[2] Das A, Rosair G M, Fallah M S E, et al. Inorg. Chem., 2006, 45:3301-3306
-
[3]
[3] Chen Q, Chang Z, Bu X H, et al. Angew. Chem. Int. Ed., 2013, 52, 11550-11553
-
[4]
[4] Hagen K S, Naik S G, Huynh B H, et al. J. Am. Chem. Soc., 2009, 131:7516-7517
-
[5]
[5] Zeng Y F, Hu X, Bu X H, et al. Chem. Soc. Rev., 2009, 38: 469-480
-
[6]
[6] Banerjee R, Phan A, Wang B, et al. Science, 2008, 319:939-943
-
[7]
[7] Férey G, Mellot-Draznieks C, Serre C, et al. Acc. Chem. Res., 2005, 38:217-225
-
[8]
[8] Wu C, Hu A, Lin W. J. Am. Chem. Soc., 2005, 127:8940-8941
-
[9]
[9] Wu C, Lin W. Angew. Chem. Int. Ed., 2007, 46:1075-1078
-
[10]
[10] Ma L, Mihalcik D J, Lin W. J. Am. Chem. Soc., 2009, 131: 4610-4612
-
[11]
[11] Chen Y Q, Li G R, Bu X H, et al. Chem. Sci., 2013, 4: 3678-368
-
[12]
[12] Zhang P, Zhang L, Lin S Y, et al. Inorg. Chem., 2013, 52: 4587-4592
-
[13]
[13] Kaminker R, Motiei L, Gulino A, et al. J. Am. Chem. Soc., 2010, 132:14554-14561
-
[14]
[14] Li J R, Tao Y, Bu X H, et al. Chem. Commun., 2007:1527-1529
-
[15]
[15] Tian D, Chen Q, Bu X H, et al. Angew. Chem. Int. Edit., 2013, DOI: 10.1002/anie.201307681
-
[16]
[16] Baur W H. Nat. Mater., 2003, 2:17-18
-
[17]
[17] Yao X Q, Cao D P, Hu J S, et al. Cryst. Growth Des., 2011, 11:231-239
-
[18]
[18] Thomas D, Serre C, Audebrand N, et al. J. Am. Chem. Soc., 2005, 127:1278812789
-
[19]
[19] Seo J S, Whang D, Lee H, et al. Nature, 2000, 404:982-986
-
[20]
[20] Ghosh S K, Zhang J P, Kitagawa S. Angew. Chem. Int. Ed., 2008, 47:3403-3406
-
[21]
[21] Fang S M, Zhang Q, Hu M, et al. Inorg. Chem., 2010, 49: 9617-9626
-
[22]
[22] Eliseeva S V, Pleshkov D N, Lyssenko K A, et al. Inorg. Chem., 2010, 49:9300-9311
-
[23]
[23] Blight B A, Stewart A F, Wang N, et al. Inorg. Chem., 2012, 51:778-780
-
[24]
[24] Zheng X Y, Ye L Q, Wen Y H. J. Mol. Struct., 2011, 987: 132-137
-
[25]
[25] Chen L. Acta Cryst. E, 2012, 68:m882
-
[26]
[26] Ji J, Yang Y F, Wen Y H. Acta Cryst. E, 2012, 68:m912-913
-
[27]
[27] Sheldrick G M. SADABS, Siemens Area Detector Absorption Corrected Software, University of Gttingen, Germany, 1996.
-
[28]
[28] Sheldrick G M. SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Gttingen, Germany, 1997.
-
[29]
[29] Liu S J, Xue L, Hu T L, et al. Dalton Trans., 2012, 41:6813-6819
-
[30]
[30] Wang X Y, Wang Z M, Gao S. Inorg. Chem., 2008, 47:5720-5726
-
[31]
[31] Cheng X H, Xue W, Zhang W X, et al. Chem. Mater., 2008, 20:5345-5350
-
[1]
-
-
[1]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[2]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[3]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[4]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[5]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[6]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[7]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[8]
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
-
[9]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[10]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[11]
Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
-
[12]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[13]
Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
-
[14]
Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
-
[15]
Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
-
[16]
Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
-
[17]
Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
-
[18]
Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu2+. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
-
[19]
Shuyan ZHAO . Field-induced CoⅡ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
-
[20]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(499)
- HTML views(66)