Citation: CHAN Chung-Sum, CHAN Kin-Shing*. Aldehydic Carbon-Hydrogen Bond Activation with Iridium(Ⅲ) Porphyrin β-Hydroxyethyl[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 75-84. doi: 10.11862/CJIC.2014.034
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Iridium(Ⅲ) porphyrin β-hydroxyethyl, IrⅢ(ttp)CH2CH2OH (ttp=5,10,15,20-tetratolylporphyrinato dianion), was found to selectively cleave the aldehydic carbon-hydrogen bonds of aryl aldehydes giving iridium acyl complexes. Iridium acyl complexes are good candidates for the studies on carbonylation and decarbonylation reactions as well as potential functionalization. The carbon-hydrogen bond activation (CHA) is proposed to occur through the initial β-hydroxyl elimination of IrⅢ(ttp)CH2CH2OH to give IrⅢ(ttp)OH, which then undergoes σ-bond metathesis with the aldehydic C-H bond.
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