Citation: ZHANG Ji-Cai, LI Ying-Nan, HUANG Di, XU Fang-Yuan, CHENG Xiao-Shan, YOU Zhong-Lu. Alternate Arrangement of Cl and Br Substituent Groups in Crystal Packing:Syntheses and Structures of Schiff Bases and Their Copper(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 425-430. doi: 10.11862/CJIC.2014.004
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Two new Schiff bases, N,N'-bis(5-chlorosalicylidene)-1,3-diaminopentane (H2CAP) and N,N'-bis(5-bromosalicylidene)-1,3-diaminopentane (H2BAP), and their copper(Ⅱ) complexes, [Cu(CAP)] (1), [Cu(BAP)] (2) and [Cu(CAP)0.5(BAP)0.5] (3), have been prepared and structurally characterized by elemental analysis, IRand electronic spectroscopy. The complexes have also been characterized by single-crystal X-ray diffraction studies. The Cu atom in each of the complexes is in a tetrahedrally distorted square planar coordination. By combination of complex 1 and 2, a new aggregation 3 was formed. There are interesting alternate arrangement of Cl and Br substituent groups in the crystal packing of the aggregation. CCDC: 889058, 1; 889059, 2; 889057, 3.
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